Inspector Parry said the couple were no longer living together and the woman had taken out an apprehended violence order.
The offence of using poison to endanger life or inflict grievous bodily harm carries a maximum sentence of 10 years' imprisonment.
The woman took the coffee jar to police. It was tested and found to contain poisonous chemicals.
girlfriend's instant coffee will face court later this month, police say.
''We searched the house and found a number of other things which go towards the police case. Those items have been tested and found to contain active ingredients in rat poison.''
He was charged with using poison to endanger life and administering poison with the intention of injuring .
Man accused of poisoning partner
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A man, 37, accused of pouring green pellets of rat poison into his Prada Bags Women
The man was granted conditional bail to appear at Camden Local Court on August 29.
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Police searched the Prada Bags Purple couple's home and allegedly found a number of other items which supported the woman's claim she had been poisoned.
The woman, 32, allegedly noticed strange coloured granules in an instant coffee jar after drinking several cups at her home in Sydney's south west on May 1.
''She noticed small, odd coloured granules in the coffee jar and obviously there was some taste issues there. Thank heavens they don't make coffee the same colour as rat poison.''
The accused was arrested after he handed himself into Narellan police station on Tuesday.
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